Growth and Structure of hcp Ti Films on Al(111) Surfaces
Y.W.Kim, G.A.White, N.R.Shivaparan, M.A.Teter, and R.J.Smith,
Department of Physics, Montana State University, Bozeman, Montana 59717*



The structure of thin Ti films grown on Al(111) surfaces at room temperature has been studied using high energy ion scattering/channeling (HEIS), x-ray photoelectron spectroscopy (XPS), low energy ion scattering (LEIS), low energy electron diffraction (LEED) and x-ray photoelectron diffraction (XPD). Our results shows that Ti grows in the SK mode on the Al(111) surface. Ti atoms form a 2-dimensional overlayer up to a deposition of about 2ML Ti, followed by 3-dimensional island growth with additional Ti deposition. The Ti islands cover the surface completely at about 12ML of Ti deposition. XPD results shows that the Ti overlayer has a well-ordered hcp Ti(0001) structure on the fcc Al(111) surface, in remarkable contrast to the fcc Ti film growth observed on Al(001) and Al(110) surfaces.

*Work supported by NSF Grant No. DMR-9710092 and NASA EPSCoR Grant NCCW-0058

Accepted for publication in Surface Review and Letters (1999)

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